What is Biodiesel?
Biodiesel is a domestically produced, renewable fuel that can be manufactured from vegetable oils, animal fats, or recycled restaurant greases. Biodiesel is safe, biodegradable, and reduces serious air pollutants such as particulates, carbon monoxide, hydrocarbons, and air toxics. Blends of 20% biodiesel with 80% petroleum diesel (B20) can generally be used in unmodified diesel engines; however, users should consult their OEM and engine warranty statement. Biodiesel can also be used in its pure form (B100), but it may require certain engine modifications to avoid maintenance and performance problems and may not be suitable for wintertime use. Users should consult their engine warranty statement.
How is Biodiesel Made?
Biodiesel fuel can be made from new or used vegetable oils and animal fats, which are nontoxic, biodegradable, renewable resources. Fats and oils are chemically reacted with an alcohol (methanol is the usual choice) to produce chemical compounds known as fatty acid methyl esters. Biodiesel is the name given to these esters when they're intended for use as fuel. Glycerol (used in pharmaceuticals and cosmetics, among other markets) is produced as a coproduct.
Biodiesel can be produced by a variety of esterification technologies. The oils and fats are filtered and preprocessed to remove water and contaminants. If free fatty acids are present, they can be removed or transformed into biodiesel using special pretreatment technologies. The pretreated oils and fats are then mixed with an alcohol (usually methanol) and a catalyst (usually sodium hydroxide). The oil molecules (triglycerides) are broken apart and reformed into methylesters and glycerol, which are then separated from each other and purified.
Approximately 55% of the biodiesel industry can use any fat or oil feedstock, including recycled cooking grease. The other half of the industry is limited to vegetable oils, the least expensive of which is soy oil. The soy industry has been the driving force behind biodiesel commercialization because of excess production capacity, product surpluses, and declining prices. Similar issues apply to the recycled grease and animal fats industry, even though these feedstocks are less expensive than soy oils.
Based on the combined resources of both industries, there is enough feedstock to supply 1.9 billion gallons of biodiesel (under policies designed to encourage biodiesel use). This represents roughly 5% of on-road diesel used in the United States.
Biodiesel Benefits
Because little fossil energy is required to move biodiesel, it is a substitute or extender for traditional petroleum diesel, and special pumps or high pressure equipment for fueling are not needed. In addition, it can be used in conventional diesel engines, so special vehicles or engines to run biodiesel do not need to be purchased. However, users should always consult with the OEM and engine warranty statement before using biodiesel.
Scientists believe carbon dioxide is one of the main greenhouse gases contributing to global warming. Neat biodiesel (100% biodiesel) reduces carbon dioxide emissions by more than 75% over petroleum diesel. Using a blend of 20% biodiesel reduces carbon dioxide emissions by 15%.
Biodiesel also produces fewer particulate matter, carbon monoxide, and sulfur dioxide emissions (all air pollutants under the Clean Air Act).
Since biodiesel can be used in conventional diesel engines, the renewable fuel can directly replace petroleum products; reducing the country's dependence on imported oil.
Biodiesel offers safety benefits over petroleum diesel because it is much less combustible, with a flash point greater than 150°C, compared to 77°C for petroleum diesel. It is safe to handle, store, and transport.